Applications: Small electronic equipment, hearing
aids, photography, alarm systems, emergency beacons, detonators, radio
microphones
This is an obsolete technology. Most if not all of the
manufacture of these cells has been stopped by government regulators. Mercury
batteries come in two main varieties: zinc/mercuric oxide and cadmium/mercuric
oxide. The zinc/mercuric oxide system has high volumetric specific energy (400
Wh/L), long storage life, and stable voltage. The cadmium/mercuric oxide system
has good high temperature and good low temperature (-55 C to +80 C, some
designs to +180 C) and has very low gas evolution.
Basic Cell Reaction
Voltage
Electrochemical
Efficiency
Zn + HgO = ZnO + Hg
1.35 V
820 mAH/g(Zn), 250 mAH/g(Hg)
Cd + HgO + H2O = Cd(OH2) + Hg
0.91 V
480 mAH/g(Cd)
The electrolytes used in mercury
cells are sodium and/or potassium hydroxide solutions, making these alkaline
cells. These cells are not rechargeable.